Products from Enzyme-Catalyzed Oxidations of Norcarenes
نویسندگان
چکیده
منابع مشابه
Inhibition of peroxidase-catalyzed oxidations.
Chance (1) has proposed that the peroxidase-catalyzed oxidation of diiydroxyfumaric acid proceeds in two steps. The first step is the oxidation of the hydrogen donor by oxygen, the reaction being catalyzed by a manganese-activated peroxidase and accompanied by the production of hydrogen peroxide. The second step is the oxidation of additional hydrogen donor by hydrogen peroxide, this reaction a...
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Norcarane, bicyclo[4.1.0]heptane, has been widely used as a mechanistic probe in studies of oxidations catalyzed by several iron-containing enzymes. We report here that, in addition to oxygenated products, norcarane is also oxidized by iron-containing enzymes in desaturase reactions that give 2-norcarene and 3-norcarene. Furthermore, secondary products from further oxidation reactions of the no...
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متن کاملEnzyme-Catalyzed Transetherification of Alkoxysilanes
We report the first evidence of an enzyme-catalyzed transetherification of model 17 alkoxysilanes. During an extensive enzymatic screening in the search for new biocatalysts 18 for silicon-oxygen bond formation we found that certain enzymes promoted the 19 transetherification of alkoxysilanes when tert-butanol or 1-octanol were used as the 20 reaction solvents. 21
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2007
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo061865j